A crystallographically characterized salt of self-generated N-protonated tetraethylurea.
نویسندگان
چکیده
The reaction of 1,1,3,3-tetraethylurea (teu) with WCl6 in dichloromethane afforded [teuH][WCl6], 1, in 50-60% yield. The X-ray structure determined for includes the first example of crystallographic characterization of a N-protonated urea. According to spectroscopic and DFT outcomes, the formation of 1 is the result of an electron transfer/C-H activation process.
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عنوان ژورنال:
- Chemical communications
دوره 51 7 شماره
صفحات -
تاریخ انتشار 2015